89Ac227 Da

Actinium

Silvery radioactive metallic element, belongs to group 3 of the periodic table. The most stable isotope, Ac-227, has a half-life of 217 years. Ac-228 (half-life of 6.13 hours) also occurs in nature. There are 22 other artificial isotopes, all radioactive and having very short half-lives. Chemistry similar to lanthanumpy. Used as a source of alpha particles. Discovered by A. Debierne in 1899.

Gallery

Actinium-225 medical radioisotope held in a v-vial at ORNL. The blue glow comes from the ionization of surrounding air by alpha particles

Oak Ridge National Laboratory, CC BY 2.0 <https://creativecommons.org/licenses/by/2.0>, via Wikimedia Commons, source: https://www.flickr.com/photos/oakridgelab/31481701837/

Bohr model of Actinium

Physical Propertiesmass · density · phase · crystal

Atomic Mass

227Da

Density

10g/cm³

Phase (STP)

Solid

Melting Point

1323.2K

Boiling Point

3473.2K

Molar Heat

0.1200J/(mol·K)

Crystal Structure

FCC

Lattice Constant

5.310Å

Atomic Radiiatomic · covalent · van der Waals

Atomic (Empirical)

195.00pm

Covalent

186.00pm

Van der Waals

247.00pm

Electronic Propertieselectronegativity · ionization · affinity

Electron Configuration

[Rn] 6d 7s2

Electron Shells

2, 8, 18, 32, 18, 9, 2

Electronegativity

1.10Pauling

Electron Affinity

0.3kJ/mol

1st Ionization Energy

5.4kJ/mol

Oxidation States

+3

Orbital DiagramAufbau · Hund's rule · Pauli exclusion

1s2
2s2
2p6
3s2
3p6
3d10
4s2
4p6
4d10
4f14
5s2
5p6
5d10
6s2
6p6
6d1
7s2

Full: 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 4f14 5s2 5p6 5d10 6s2 6p6 6d1 7s2Short: [Rn] 6d 7s2

Ionization Energies (89 known)

1st5.4 kJ/mol2nd11.8 kJ/mol3rd17.4 kJ/mol4th44.8 kJ/mol5th55.0 kJ/mol6th67.0 kJ/mol7th79.0 kJ/mol8th98.9 kJ/mol9th113.9 kJ/mol10th143.9 kJ/mol11th161.1 kJ/mol12th233.0 kJ/mol13th255.0 kJ/mol14th279.0 kJ/mol15th305.0 kJ/mol16th330.0 kJ/mol17th355.0 kJ/mol18th390.0 kJ/mol19th416.0 kJ/mol20th444.0 kJ/mol21th470.0 kJ/mol22th610.0 kJ/mol23th640.0 kJ/mol24th670.0 kJ/mol25th710.0 kJ/mol26th780.0 kJ/mol27th820.0 kJ/mol28th920.0 kJ/mol29th950.0 kJ/mol30th1030.0 kJ/mol31th1100.0 kJ/mol32th1170.0 kJ/mol33th1240.0 kJ/mol34th1310.0 kJ/mol35th1380.0 kJ/mol36th1460.0 kJ/mol37th1530.0 kJ/mol38th1610.0 kJ/mol39th1680.0 kJ/mol40th1750.0 kJ/mol41th1820.0 kJ/mol42th1900.0 kJ/mol43th1970.0 kJ/mol44th2298.0 kJ/mol45th2362.0 kJ/mol46th2430.0 kJ/mol47th2503.0 kJ/mol48th2572.0 kJ/mol49th2639.0 kJ/mol50th2762.0 kJ/mol51th2833.0 kJ/mol52th2908.0 kJ/mol53th2980.0 kJ/mol54th3264.0 kJ/mol55th3334.0 kJ/mol56th3409.0 kJ/mol57th3479.0 kJ/mol58th3811.0 kJ/mol59th3893.0 kJ/mol60th4093.0 kJ/mol61th4175.0 kJ/mol62th6767.0 kJ/mol63th6923.0 kJ/mol64th7088.0 kJ/mol65th7265.0 kJ/mol66th7430.0 kJ/mol67th7600.0 kJ/mol68th7950.0 kJ/mol69th8120.0 kJ/mol70th8310.0 kJ/mol71th8480.0 kJ/mol72th8970.0 kJ/mol73th9120.0 kJ/mol74th9290.0 kJ/mol75th9440.0 kJ/mol76th10480.0 kJ/mol77th10660.0 kJ/mol78th11030.0 kJ/mol79th11200.0 kJ/mol80th23480.0 kJ/mol81th23890.0 kJ/mol82th24340.0 kJ/mol83th24760.0 kJ/mol84th28610.0 kJ/mol85th29160.0 kJ/mol86th29850.0 kJ/mol87th30293.1 kJ/mol88th119945.7 kJ/mol89th122063.1 kJ/molSuccessive Ionization Energies

Emission Spectrumvisible range · characteristic spectral lines

408
584
Ac emission
380nm750nm
408.4 nm(100%)583.9 nm(40%)

Abundanceby mass

🌍Earth's Crust
5.5 ppt
🌊Ocean
Universe
🧬Human Body

Log scale · ppm = parts per million by mass

Biological Role

No biological role

Radioactive. Ac-225 studied for targeted alpha therapy against cancer.

Discovery

Discovered By

André Debierne

Named By

Year

1899

Nuclear Data

Known Isotopes

33

Stable Isotopes

0

Stable Mass Numbers

None

Isotopes of Ac33 known

NuclideZNMass (AMU)Half-lifeDecayAbundance
205Ac89116205.01514480.0 msα (1%), β⁺9/2-
206Ac89117206.01447625.0 msα (1%), β⁺3+
207Ac89118207.01196631.0 msα (1%)9/2-
235Ac89146235.0508401.03 minβ⁻ (1%)1/2+
236Ac89147236.0549884.50 minβ⁻ (1%)3+
237Ac89148237.057993Unknownβ⁻1/2+
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