94Pu244 Da

Plutonium

Dense silvery radioactive metallic transuranic element, belongs to the actinoids. Pu-244 is the most stable isotope with a half-life of 7.6*10^7 years. Thirteen isotopes are known. Pu-239 is the most important, it undergoes nuclear fission with slow neutrons and is hence important to nuclear weapons and reactors. Plutonium production is monitored down to the gram to prevent military misuse. First produced by Gleen T. Seaborg, Edwin M. McMillan, J.W. Kennedy and A.C. Wahl in 1940.

Gallery

Plutonium Ring

Los Alamos National Laboratory, Attribution, via Wikimedia Commons

Bohr model of Plutonium

Physical Propertiesmass · density · phase · crystal

Atomic Mass

244Da

Density

19.7000g/cm³

Phase (STP)

Solid

Melting Point

913.1K

Boiling Point

3501.2K

Molar Heat

Crystal Structure

MCL

Atomic Radiiatomic · covalent · van der Waals

Atomic (Empirical)

175.00pm

Covalent

172.00pm

Van der Waals

243.00pm

Electronic Propertieselectronegativity · ionization · affinity

Electron Configuration

[Rn] 5f6 7s2

Electron Shells

2, 8, 18, 32, 24, 8, 2

Electronegativity

1.30Pauling

Electron Affinity

1st Ionization Energy

6.0kJ/mol

Oxidation States

+3, +4, +5, +6, +7

Orbital DiagramAufbau · Hund's rule · Pauli exclusion

1s2
2s2
2p6
3s2
3p6
3d10
4s2
4p6
4d10
4f14
5s2
5p6
5d10
6s2
6p6
5f6
7s2

Full: 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 4f14 5s2 5p6 5d10 6s2 6p6 5f6 7s2Short: [Rn] 5f6 7s2

Ionization Energies (94 known)

1st6.0 kJ/mol2nd11.5 kJ/mol3rd21.1 kJ/mol4th35.0 kJ/mol5th49.0 kJ/mol6th80.0 kJ/mol7th95.0 kJ/mol8th109.0 kJ/mol9th124.0 kJ/mol10th139.0 kJ/mol11th159.0 kJ/mol12th179.0 kJ/mol13th200.0 kJ/mol14th219.0 kJ/mol15th258.0 kJ/mol16th278.0 kJ/mol17th389.0 kJ/mol18th416.0 kJ/mol19th444.0 kJ/mol20th474.0 kJ/mol21th503.0 kJ/mol22th532.0 kJ/mol23th575.0 kJ/mol24th605.0 kJ/mol25th637.0 kJ/mol26th668.0 kJ/mol27th820.0 kJ/mol28th850.0 kJ/mol29th890.0 kJ/mol30th930.0 kJ/mol31th1030.0 kJ/mol32th1070.0 kJ/mol33th1180.0 kJ/mol34th1220.0 kJ/mol35th1340.0 kJ/mol36th1420.0 kJ/mol37th1500.0 kJ/mol38th1580.0 kJ/mol39th1660.0 kJ/mol40th1740.0 kJ/mol41th1820.0 kJ/mol42th1890.0 kJ/mol43th1990.0 kJ/mol44th2070.0 kJ/mol45th2150.0 kJ/mol46th2230.0 kJ/mol47th2310.0 kJ/mol48th2390.0 kJ/mol49th2774.0 kJ/mol50th2844.0 kJ/mol51th2918.0 kJ/mol52th2997.0 kJ/mol53th3072.0 kJ/mol54th3146.0 kJ/mol55th3290.0 kJ/mol56th3366.0 kJ/mol57th3449.0 kJ/mol58th3527.0 kJ/mol59th3836.0 kJ/mol60th3911.0 kJ/mol61th3993.0 kJ/mol62th4068.0 kJ/mol63th4496.0 kJ/mol64th4585.0 kJ/mol65th4807.0 kJ/mol66th4890.0 kJ/mol67th7830.0 kJ/mol68th7990.0 kJ/mol69th8170.0 kJ/mol70th8360.0 kJ/mol71th8540.0 kJ/mol72th8710.0 kJ/mol73th9130.0 kJ/mol74th9310.0 kJ/mol75th9520.0 kJ/mol76th9700.0 kJ/mol77th10230.0 kJ/mol78th10390.0 kJ/mol79th10570.0 kJ/mol80th10730.0 kJ/mol81th12060.0 kJ/mol82th12260.0 kJ/mol83th12660.0 kJ/mol84th12840.0 kJ/mol85th26480.0 kJ/mol86th26920.0 kJ/mol87th27400.0 kJ/mol88th27840.0 kJ/mol89th32800.0 kJ/mol90th33400.0 kJ/mol91th34100.0 kJ/mol92th34625.8 kJ/mol93th136305.1 kJ/mol94th138640.2 kJ/molSuccessive Ionization Energies

Emission Spectrumvisible range · characteristic spectral lines

564
585
587
Pu emission
380nm750nm
564.0 nm(100%)585.0 nm(50%)587.0 nm(40%)

Abundanceby mass

Biological Role

Toxic

Extremely toxic due to radioactivity. Alpha emitter that concentrates in bone.

Discovery

Discovered By

G.T.Seaborg, J.W.Kennedy, E.M.McMillan, A.C.Wohl

Named By

Year

1940

Nuclear Data

Known Isotopes

27

Stable Isotopes

0

Stable Mass Numbers

None

Isotopes of Pu27 known

NuclideZNMass (AMU)Half-lifeDecayAbundance
221Pu94127221.038572Unknownα, SF9/2+
222Pu94128222.037638Unknownα, SF0+
223Pu94129223.038777Unknownα, SF9/2+
245Pu94151245.06782510.5 hβ⁻ (1%)9/2-
246Pu94152246.07020410.8 dβ⁻ (1%)0+
247Pu94153247.0743002.27 dβ⁻ (1%)1/2+
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