18Ar39.9480 Da

Argon

Monatomic noble gas. Makes up 0.93% of the air. Colourless, odorless. Is inert and has no true compounds. Lord Rayleigh and Sir william Ramsey identified argon in 1894.

Gallery

Vial of glowing ultrapure argon. Original size in cm: 1 x 5

Jurii, CC BY 3.0 <https://creativecommons.org/licenses/by/3.0>, via Wikimedia Commons, source: https://images-of-elements.com/argon.php

Bohr model of Argon
Emission spectrum of Argon

Emission spectrum

Physical Propertiesmass · density · phase · crystal

Atomic Mass

39.9480Da

Density

0.0016g/L

Phase (STP)

Gas

Melting Point

83.8K

Boiling Point

87.3K

Molar Heat

0.5200J/(mol·K)

Crystal Structure

FCC

Lattice Constant

5.260Å

Atomic Radiiatomic · covalent · van der Waals

Atomic (Empirical)

71.00pm

Covalent

96.00pm

Van der Waals

188.00pm

Electronic Propertieselectronegativity · ionization · affinity

Electron Configuration

[Ne] 3s2 3p6

Electron Shells

2, 8, 8

Electronegativity

Electron Affinity

-11.5kJ/mol

1st Ionization Energy

15.8kJ/mol

Oxidation States

0

Orbital DiagramAufbau · Hund's rule · Pauli exclusion

1s2
2s2
2p6
3s2
3p6

Full: 1s2 2s2 2p6 3s2 3p6Short: [Ne] 3s2 3p6

Ionization Energies (18 known)

1st15.8 kJ/mol2nd27.6 kJ/mol3rd40.7 kJ/mol4th59.6 kJ/mol5th74.8 kJ/mol6th91.3 kJ/mol7th124.4 kJ/mol8th143.5 kJ/mol9th422.6 kJ/mol10th479.8 kJ/mol11th540.4 kJ/mol12th619.0 kJ/mol13th685.5 kJ/mol14th755.1 kJ/mol15th855.5 kJ/mol16th918.4 kJ/mol17th4120.7 kJ/mol18th4426.2 kJ/molSuccessive Ionization Energies

Emission Spectrumvisible range · characteristic spectral lines

697
707
738
416
420
Ar emission
380nm750nm
696.5 nm(100%)706.7 nm(70%)750.4 nm(50%)738.4 nm(50%)415.9 nm(30%)420.1 nm(30%)

Abundanceby mass

🌍Earth's Crust
3.5 ppm
🌊Ocean
450.0 ppb
Universe
77.0 ppm
🧬Human Body

Log scale · ppm = parts per million by mass

Biological Role

No biological role

Inert noble gas with no biological role.

Discovery

Discovered By

Sir William Ramsey, Baron Rayleigh

Named By

Year

1894

Nuclear Data

Known Isotopes

26

Stable Isotopes

4

Stable Mass Numbers

29, 36, 38, 40

Natural isotopic abundance (IUPAC recommended values)

Isotopes of Ar26 known

NuclideZNMass (AMU)Half-lifeDecayAbundance
29Arstable181129.040761Stable2p (1%)5/2+
30Ar181230.023694Unknown2p (1%)0+
31Ar181331.01215815.0 msβ⁺ (1%), β⁺p (0.6829999999999999%), 2p (0.09%), B+pA (0.0038%), 3p (0.0007000000000000001%), β⁺α (0.0003%), 2p (0.000005999999999999999%)5/2+
36Arstable181835.967545Stable2β⁺0+33.3600%
38Arstable182037.962732Stablestable (1%)0+6.2900%
40Arstable182239.962383Stablestable (1%)0+9960.3500%
52Ar183451.998519Unknownβ⁻, β⁻n, 2n0+
53Ar183553.007290Unknownβ⁻, β⁻n, 2n5/2-
54Ar183654.013484Unknownβ⁻, β⁻n, 2n0+
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