19K39.0983 Da

Potassium

Soft silvery metallic element belonging to group 1 of the periodic table (alkali metals). Occurs naturally in seawater and a many minerals. Highly reactive, chemically, it resembles sodium in its behavior and compounds. Discovered by Sir Humphry Davy in 1807.

Gallery

Potassium Pieces

Dnn87, CC BY 3.0 <https://creativecommons.org/licenses/by/3.0>, via Wikimedia Commons

Bohr model of Potassium
Emission spectrum of Potassium

Emission spectrum

Physical Propertiesmass · density · phase · crystal

Atomic Mass

39.0983Da

Density

0.8900g/cm³

Phase (STP)

Solid

Melting Point

336.6K

Boiling Point

1032.2K

Molar Heat

0.7570J/(mol·K)

Crystal Structure

BCC

Lattice Constant

5.230Å

Atomic Radiiatomic · covalent · van der Waals

Atomic (Empirical)

220.00pm

Covalent

196.00pm

Van der Waals

275.00pm

Electronic Propertieselectronegativity · ionization · affinity

Electron Configuration

[Ar] 4s

Electron Shells

2, 8, 8, 1

Electronegativity

0.82Pauling

Electron Affinity

0.5kJ/mol

1st Ionization Energy

4.3kJ/mol

Oxidation States

+1

Orbital DiagramAufbau · Hund's rule · Pauli exclusion

↑↓
1s2
↑↓
2s2
↑↓
↑↓
↑↓
2p6
↑↓
3s2
↑↓
↑↓
↑↓
3p6
↑
4s1

Full: 1s2 2s2 2p6 3s2 3p6 4s1Short: [Ar] 4s

Ionization Energies (19 known)

1st4.3 kJ/mol2nd31.6 kJ/mol3rd45.8 kJ/mol4th60.9 kJ/mol5th82.7 kJ/mol6th99.4 kJ/mol7th117.6 kJ/mol8th154.9 kJ/mol9th175.8 kJ/mol10th503.7 kJ/mol11th565.6 kJ/mol12th631.1 kJ/mol13th714.7 kJ/mol14th786.3 kJ/mol15th860.9 kJ/mol16th967.7 kJ/mol17th1034.5 kJ/mol18th4610.8 kJ/mol19th4934.0 kJ/molSuccessive Ionization Energies

Emission Spectrumvisible range · characteristic spectral lines

404
405
K emission
380nm750nm
766.5 nm(100%)769.9 nm(80%)404.4 nm(20%)404.7 nm(15%)

Abundanceby mass

🌍Earth's Crust
20.9‰
🌊Ocean
399.0 ppm
✨Universe
3.0 ppm
🧬Human Body
2.0‰

Log scale · ppm = parts per million by mass

Biological Role

Essential

Major intracellular cation. Essential for nerve function, muscle contraction, and heart rhythm.

Discovery

Discovered By

Sir Humphrey Davy

Named By

—

Year

1807

Nuclear Data

Known Isotopes

29

Stable Isotopes

5

Stable Mass Numbers

32, 33, 34, 39, 41

Natural isotopic abundance (IUPAC recommended values)

Isotopes of K29 known

NuclideZNMass (AMU)Half-lifeDecayJπAbundance
31K191231.036780Unknown3p (1%)3/2+—
32Kstable191332.023607Stablep1+—
33Kstable191433.008095Stablep3/2+—
34Kstable191533.998690Stablep1+—
39Kstable192038.963706Stablestable (1%)3/2+9325.8100%
40K192139.9639981.25 Gyβ⁻ (0.8928%), β⁺ (0.1072%)4-1.1700%
41Kstable192240.961825Stablestable (1%)3/2+673.0200%
57K193857.015169Unknownβ⁻, β⁻n, 2n3/2+—
58K193958.023543Unknownβ⁻, β⁻n, 2n2-—
59K194059.030864Unknownβ⁻, β⁻n, 2n3/2+—
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