19K39.0983 Da

Potassium

Soft silvery metallic element belonging to group 1 of the periodic table (alkali metals). Occurs naturally in seawater and a many minerals. Highly reactive, chemically, it resembles sodium in its behavior and compounds. Discovered by Sir Humphry Davy in 1807.

Gallery

Potassium Pieces

Dnn87, CC BY 3.0 <https://creativecommons.org/licenses/by/3.0>, via Wikimedia Commons

Bohr model of Potassium
Emission spectrum of Potassium

Emission spectrum

Physical Propertiesmass · density · phase · crystal

Atomic Mass

39.0983Da

Density

0.8900g/cm³

Phase (STP)

Solid

Melting Point

336.6K

Boiling Point

1032.2K

Molar Heat

0.7570J/(mol·K)

Crystal Structure

BCC

Lattice Constant

5.230Å

Atomic Radiiatomic · covalent · van der Waals

Atomic (Empirical)

220.00pm

Covalent

196.00pm

Van der Waals

275.00pm

Electronic Propertieselectronegativity · ionization · affinity

Electron Configuration

[Ar] 4s

Electron Shells

2, 8, 8, 1

Electronegativity

0.82Pauling

Electron Affinity

0.5kJ/mol

1st Ionization Energy

4.3kJ/mol

Oxidation States

+1

Orbital DiagramAufbau · Hund's rule · Pauli exclusion

1s2
2s2
2p6
3s2
3p6
4s1

Full: 1s2 2s2 2p6 3s2 3p6 4s1Short: [Ar] 4s

Ionization Energies (19 known)

1st4.3 kJ/mol2nd31.6 kJ/mol3rd45.8 kJ/mol4th60.9 kJ/mol5th82.7 kJ/mol6th99.4 kJ/mol7th117.6 kJ/mol8th154.9 kJ/mol9th175.8 kJ/mol10th503.7 kJ/mol11th565.6 kJ/mol12th631.1 kJ/mol13th714.7 kJ/mol14th786.3 kJ/mol15th860.9 kJ/mol16th967.7 kJ/mol17th1034.5 kJ/mol18th4610.8 kJ/mol19th4934.0 kJ/molSuccessive Ionization Energies

Emission Spectrumvisible range · characteristic spectral lines

404
405
K emission
380nm750nm
766.5 nm(100%)769.9 nm(80%)404.4 nm(20%)404.7 nm(15%)

Abundanceby mass

🌍Earth's Crust
20.9‰
🌊Ocean
399.0 ppm
Universe
3.0 ppm
🧬Human Body
2.0‰

Log scale · ppm = parts per million by mass

Biological Role

Essential

Major intracellular cation. Essential for nerve function, muscle contraction, and heart rhythm.

Discovery

Discovered By

Sir Humphrey Davy

Named By

Year

1807

Nuclear Data

Known Isotopes

29

Stable Isotopes

5

Stable Mass Numbers

32, 33, 34, 39, 41

Natural isotopic abundance (IUPAC recommended values)

Isotopes of K29 known

NuclideZNMass (AMU)Half-lifeDecayAbundance
31K191231.036780Unknown3p (1%)3/2+
32Kstable191332.023607Stablep1+
33Kstable191433.008095Stablep3/2+
34Kstable191533.998690Stablep1+
39Kstable192038.963706Stablestable (1%)3/2+9325.8100%
40K192139.9639981.25 Gyβ⁻ (0.8928%), β⁺ (0.1072%)4-1.1700%
41Kstable192240.961825Stablestable (1%)3/2+673.0200%
57K193857.015169Unknownβ⁻, β⁻n, 2n3/2+
58K193958.023543Unknownβ⁻, β⁻n, 2n2-
59K194059.030864Unknownβ⁻, β⁻n, 2n3/2+
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