Cesium
Soft silvery-white metallic element belonging to group 1 of the periodic table. One of the three metals which are liquid at room temperature. Cs-133 is the natural, and only stable, isotope. Fifteen other radioisotopes exist. Caesium reacts explosively with cold water, and ice at temperatures above 157K. Caesium hydroxide is the strongest base known. Caesium is the most electropositive, most alkaline and has the least ionization potential of all the elements. Known uses include the basis of atomic clocks, catalyst for the hydrogenation of some organic compounds, and in photoelectric cells. Caesium was discovered by Gustav Kirchoff and Robert Bunsen in Germany in 1860 spectroscopically. Its identification was based upon the bright blue lines in its spectrum. The name comes from the latin word caesius, which means sky blue. Caesium should be considered highly toxic. Some of the radioisotopes are even more toxic.
Gallery

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Physical Propertiesmass · density · phase · crystal
Atomic Mass
132.9055Da
Density
1.8730g/cm³
Phase (STP)
Solid
Melting Point
301.6K
Boiling Point
944.1K
Molar Heat
0.2420J/(mol·K)
Crystal Structure
BCC
Lattice Constant
6.050Å
Atomic Radiiatomic · covalent · van der Waals
Atomic (Empirical)
260.00pm
Covalent
232.00pm
Van der Waals
343.00pm
Electronic Propertieselectronegativity · ionization · affinity
Electron Configuration
[Xe] 6s
Electron Shells
2, 8, 18, 18, 8, 1
Electronegativity
0.79Pauling
Electron Affinity
0.5kJ/mol
1st Ionization Energy
3.9kJ/mol
Oxidation States
+1
Orbital DiagramAufbau · Hund's rule · Pauli exclusion
Full: 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 5s2 5p6 6s1Short: [Xe] 6s
Ionization Energies (55 known)
Emission Spectrumvisible range · characteristic spectral lines
Abundanceby mass
Log scale · ppm = parts per million by mass
Biological Role
No known biological role. Cs-137 is a dangerous radioactive contaminant.
Discovery
Discovered By
Gustov Kirchoff, Robert Bunsen
Named By
—
Year
1860
Nuclear Data
Known Isotopes
42
Stable Isotopes
1
Stable Mass Numbers
133
Natural isotopic abundance (IUPAC recommended values)
Isotopes of Cs42 known
| Nuclide | Z | N | Mass (AMU) | Half-life | Decay | Jπ | Abundance |
|---|---|---|---|---|---|---|---|
| 111Cs | 55 | 56 | 110.953945 | Unknown | p | 3/2+ | — |
| 112Cs | 55 | 57 | 111.950172 | 490 μs | p (1%), α (0.0026%) | 1+ | — |
| 113Cs | 55 | 58 | 112.944428 | 16.9 μs | p (1%) | 3/2+ | — |
| 133Csstable | 55 | 78 | 132.905452 | Stable | stable (1%) | 7/2+ | 10000.0000% |
| 150Cs | 55 | 95 | 149.959023 | 81.0 ms | β⁻ (1%), β⁻n (0.44%), 2n | 2- | — |
| 151Cs | 55 | 96 | 150.963199 | 59.0 ms | β⁻ (1%), β⁻n, 2n | 3/2+ | — |
| 152Cs | 55 | 97 | 151.968728 | Unknown | β⁻, β⁻n | — | — |