55Cs132.9055 Da

Cesium

Soft silvery-white metallic element belonging to group 1 of the periodic table. One of the three metals which are liquid at room temperature. Cs-133 is the natural, and only stable, isotope. Fifteen other radioisotopes exist. Caesium reacts explosively with cold water, and ice at temperatures above 157K. Caesium hydroxide is the strongest base known. Caesium is the most electropositive, most alkaline and has the least ionization potential of all the elements. Known uses include the basis of atomic clocks, catalyst for the hydrogenation of some organic compounds, and in photoelectric cells. Caesium was discovered by Gustav Kirchoff and Robert Bunsen in Germany in 1860 spectroscopically. Its identification was based upon the bright blue lines in its spectrum. The name comes from the latin word caesius, which means sky blue. Caesium should be considered highly toxic. Some of the radioisotopes are even more toxic.

Gallery

Cesium/Caesium metal

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Bohr model of Cesium

Physical Propertiesmass · density · phase · crystal

Atomic Mass

132.9055Da

Density

1.8730g/cm³

Phase (STP)

Solid

Melting Point

301.6K

Boiling Point

944.1K

Molar Heat

0.2420J/(mol·K)

Crystal Structure

BCC

Lattice Constant

6.050Å

Atomic Radiiatomic · covalent · van der Waals

Atomic (Empirical)

260.00pm

Covalent

232.00pm

Van der Waals

343.00pm

Electronic Propertieselectronegativity · ionization · affinity

Electron Configuration

[Xe] 6s

Electron Shells

2, 8, 18, 18, 8, 1

Electronegativity

0.79Pauling

Electron Affinity

0.5kJ/mol

1st Ionization Energy

3.9kJ/mol

Oxidation States

+1

Orbital DiagramAufbau · Hund's rule · Pauli exclusion

1s2
2s2
2p6
3s2
3p6
3d10
4s2
4p6
4d10
5s2
5p6
6s1

Full: 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 5s2 5p6 6s1Short: [Xe] 6s

Ionization Energies (55 known)

1st3.9 kJ/mol2nd23.2 kJ/mol3rd33.2 kJ/mol4th43.0 kJ/mol5th56.0 kJ/mol6th69.1 kJ/mol7th82.9 kJ/mol8th110.1 kJ/mol9th125.6 kJ/mol10th213.3 kJ/mol11th233.0 kJ/mol12th261.0 kJ/mol13th289.0 kJ/mol14th316.0 kJ/mol15th352.0 kJ/mol16th382.0 kJ/mol17th413.0 kJ/mol18th445.0 kJ/mol19th476.0 kJ/mol20th597.0 kJ/mol21th629.0 kJ/mol22th666.0 kJ/mol23th700.0 kJ/mol24th753.0 kJ/mol25th791.0 kJ/mol26th875.0 kJ/mol27th916.1 kJ/mol28th1592.0 kJ/mol29th1672.0 kJ/mol30th1757.0 kJ/mol31th1848.0 kJ/mol32th1936.0 kJ/mol33th2029.0 kJ/mol34th2137.0 kJ/mol35th2230.0 kJ/mol36th2329.0 kJ/mol37th2422.0 kJ/mol38th2683.0 kJ/mol39th2767.0 kJ/mol40th2859.0 kJ/mol41th2945.0 kJ/mol42th3118.0 kJ/mol43th3214.0 kJ/mol44th3392.0 kJ/mol45th3485.0 kJ/mol46th7989.0 kJ/mol47th8224.0 kJ/mol48th8484.0 kJ/mol49th8726.0 kJ/mol50th9350.0 kJ/mol51th9629.0 kJ/mol52th9974.0 kJ/mol53th10208.8 kJ/mol54th41861.1 kJ/mol55th42913.1 kJ/molSuccessive Ionization Energies

Emission Spectrumvisible range · characteristic spectral lines

456
459
621
672
Cs emission
380nm750nm
455.5 nm(100%)459.3 nm(30%)621.3 nm(20%)672.3 nm(15%)

Abundanceby mass

🌍Earth's Crust
3.0 ppm
🌊Ocean
300.0 ppt
Universe
800.0 ppt
🧬Human Body
20.0 ppb

Log scale · ppm = parts per million by mass

Biological Role

No biological role

No known biological role. Cs-137 is a dangerous radioactive contaminant.

Discovery

Discovered By

Gustov Kirchoff, Robert Bunsen

Named By

Year

1860

Nuclear Data

Known Isotopes

42

Stable Isotopes

1

Stable Mass Numbers

133

Natural isotopic abundance (IUPAC recommended values)

Isotopes of Cs42 known

NuclideZNMass (AMU)Half-lifeDecayAbundance
111Cs5556110.953945Unknownp3/2+
112Cs5557111.950172490 μsp (1%), α (0.0026%)1+
113Cs5558112.94442816.9 μsp (1%)3/2+
133Csstable5578132.905452Stablestable (1%)7/2+10000.0000%
150Cs5595149.95902381.0 msβ⁻ (1%), β⁻n (0.44%), 2n2-
151Cs5596150.96319959.0 msβ⁻ (1%), β⁻n, 2n3/2+
152Cs5597151.968728Unknownβ⁻, β⁻n
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