26Fe55.8450 Da

Iron

Silvery malleable and ductile metallic transition element. Has nine isotopes and is the fourth most abundant element in the earth's crust. Required by living organisms as a trace element (used in hemoglobin in humans.) Quite reactive, oxidizes in moist air, displaces hydrogen from dilute acids and combines with nonmetallic elements.

Gallery

Fragments of an iron meteorite, about 92% iron. Original size of the single pieces in cm: 0.4 - 0.8

Chemical ELements A Virtual Museum, CC BY 3.0 <https://creativecommons.org/licenses/by/3.0> source: https://images-of-elements.com/iron.php

Bohr model of Iron
Emission spectrum of Iron

Emission spectrum

Physical Propertiesmass · density · phase · crystal

Atomic Mass

55.8450Da

Density

7.8700g/cm³

Phase (STP)

Solid

Melting Point

1811.2K

Boiling Point

3134.2K

Molar Heat

0.4490J/(mol·K)

Crystal Structure

BCC

Lattice Constant

2.870Å

Atomic Radiiatomic · covalent · van der Waals

Atomic (Empirical)

140.00pm

Covalent

116.00pm

Van der Waals

204.00pm

Electronic Propertieselectronegativity · ionization · affinity

Electron Configuration

[Ar] 3d6 4s2

Electron Shells

2, 8, 14, 2

Electronegativity

1.83Pauling

Electron Affinity

0.2kJ/mol

1st Ionization Energy

7.9kJ/mol

Oxidation States

-4, -2, -1, 0, +1, +2, +3, +4, +5, +6

Orbital DiagramAufbau · Hund's rule · Pauli exclusion

1s2
2s2
2p6
3s2
3p6
3d6
4s2

Full: 1s2 2s2 2p6 3s2 3p6 3d6 4s2Short: [Ar] 3d6 4s2

Ionization Energies (26 known)

1st7.9 kJ/mol2nd16.2 kJ/mol3rd30.7 kJ/mol4th54.9 kJ/mol5th75.0 kJ/mol6th99.0 kJ/mol7th125.0 kJ/mol8th151.1 kJ/mol9th233.6 kJ/mol10th262.1 kJ/mol11th290.9 kJ/mol12th330.8 kJ/mol13th361.0 kJ/mol14th392.2 kJ/mol15th456.2 kJ/mol16th489.3 kJ/mol17th1262.7 kJ/mol18th1357.8 kJ/mol19th1460.0 kJ/mol20th1575.6 kJ/mol21th1687.0 kJ/mol22th1798.4 kJ/mol23th1950.4 kJ/mol24th2045.8 kJ/mol25th8828.2 kJ/mol26th9277.7 kJ/molSuccessive Ionization Energies

Emission Spectrumvisible range · characteristic spectral lines

438
405
382
527
517
431
Fe emission
380nm750nm
382.0 nm(100%)438.4 nm(80%)404.6 nm(70%)430.8 nm(50%)527.0 nm(40%)516.7 nm(30%)

Abundanceby mass

🌍Earth's Crust
56.3‰
🌊Ocean
2.0 ppb
Universe
1.1‰
🧬Human Body
60.0 ppm

Log scale · ppm = parts per million by mass

Biological Role

Essential

Core of hemoglobin and myoglobin for oxygen transport. Deficiency causes anemia.

Discovery

Discovered By

Known to the ancients.

Named By

Year

Nuclear Data

Known Isotopes

32

Stable Isotopes

4

Stable Mass Numbers

54, 56, 57, 58

Natural isotopic abundance (IUPAC recommended values)

Isotopes of Fe32 known

NuclideZNMass (AMU)Half-lifeDecayAbundance
45Fe261945.0154672.50 ms2p (0.7%), β⁺ (0.3%), β⁺p (0.18899999999999997%), 2p (0.078%)3/2+
46Fe262046.00129913.0 msβ⁺ (1%), β⁺p (0.787%), 2p0+
47Fe262146.99234621.9 msβ⁺ (1%), β⁺p (0.884%)7/2-
54Festable262853.939608Stable2β⁺0+584.5000%
56Festable263055.934936Stablestable (1%)0+9175.4000%
57Festable263156.935392Stablestable (1%)1/2-211.9000%
58Festable263257.933274Stablestable (1%)0+28.2000%
74Fe264873.9778215.00 msβ⁻ (1%), β⁻n, 2n0+
75Fe264974.984219Unknownβ⁻, β⁻n, 2n9/2+
76Fe265075.988631Unknownβ⁻0+
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