25Mn54.9380 Da

Manganese

Grey brittle metallic transition element. Rather electropositive, combines with some non-metals when heated. Discovered in 1774 by Scheele.

Gallery

Two Oieces of Manganese Metal

W. Oelen, CC BY-SA 3.0 <https://creativecommons.org/licenses/by-sa/3.0>, via Wikimedia Commons

Bohr model of Manganese

Physical Propertiesmass · density · phase · crystal

Atomic Mass

54.9380Da

Density

7.3000g/cm³

Phase (STP)

Solid

Melting Point

1519.2K

Boiling Point

2334.2K

Molar Heat

0.4790J/(mol·K)

Crystal Structure

CUB

Lattice Constant

8.890Å

Atomic Radiiatomic · covalent · van der Waals

Atomic (Empirical)

140.00pm

Covalent

119.00pm

Van der Waals

205.00pm

Electronic Propertieselectronegativity · ionization · affinity

Electron Configuration

[Ar] 3d5 4s2

Electron Shells

2, 8, 13, 2

Electronegativity

1.55Pauling

Electron Affinity

1st Ionization Energy

7.4kJ/mol

Oxidation States

-3, -2, -1, 0, +1, +2, +3, +4, +5, +6, +7

Orbital DiagramAufbau · Hund's rule · Pauli exclusion

1s2
2s2
2p6
3s2
3p6
3d5
4s2

Full: 1s2 2s2 2p6 3s2 3p6 3d5 4s2Short: [Ar] 3d5 4s2

Ionization Energies (25 known)

1st7.4 kJ/mol2nd15.6 kJ/mol3rd33.7 kJ/mol4th51.2 kJ/mol5th72.4 kJ/mol6th95.6 kJ/mol7th119.2 kJ/mol8th195.5 kJ/mol9th221.9 kJ/mol10th248.6 kJ/mol11th286.1 kJ/mol12th314.4 kJ/mol13th343.6 kJ/mol14th402.9 kJ/mol15th435.2 kJ/mol16th1133.7 kJ/mol17th1224.1 kJ/mol18th1320.3 kJ/mol19th1430.9 kJ/mol20th1537.2 kJ/mol21th1643.2 kJ/mol22th1788.7 kJ/mol23th1879.9 kJ/mol24th8140.8 kJ/mol25th8572.0 kJ/molSuccessive Ionization Energies

Emission Spectrumvisible range · characteristic spectral lines

403
403
403
475
482
Mn emission
380nm750nm
403.1 nm(100%)403.4 nm(80%)403.3 nm(70%)475.4 nm(30%)482.4 nm(20%)

Abundanceby mass

🌍Earth's Crust
950.0 ppm
🌊Ocean
200.0 ppt
Universe
8.0 ppm
🧬Human Body
200.0 ppb

Log scale · ppm = parts per million by mass

Biological Role

Essential (trace)

Cofactor for superoxide dismutase and other enzymes. Essential for bone formation.

Discovery

Discovered By

Johann Gahn

Named By

Year

1774

Nuclear Data

Known Isotopes

31

Stable Isotopes

4

Stable Mass Numbers

43, 44, 45, 55

Natural isotopic abundance (IUPAC recommended values)

Isotopes of Mn31 known

NuclideZNMass (AMU)Half-lifeDecayAbundance
43Mnstable251843.018647Stablep5/2-
44Mnstable251944.008009Stablep2-
45Mnstable252044.994654Stablep5/2-
55Mnstable253054.938043Stablestable (1%)5/2-10000.0000%
71Mn254670.982158Unknownβ⁻, β⁻n, 2n5/2-
72Mn254771.988009Unknownβ⁻, β⁻n, 2n
73Mn254872.992807Unknownβ⁻5/2-
Wikipedia →Data: Bowserinator · IAEA NDS · mendeleev