25Mn54.9380 Da

Manganese

Grey brittle metallic transition element. Rather electropositive, combines with some non-metals when heated. Discovered in 1774 by Scheele.

Gallery

Two Oieces of Manganese Metal

W. Oelen, CC BY-SA 3.0 <https://creativecommons.org/licenses/by-sa/3.0>, via Wikimedia Commons

Bohr model of Manganese

Physical Propertiesmass · density · phase · crystal

Atomic Mass

54.9380Da

Density

7.3000g/cm³

Phase (STP)

Solid

Melting Point

1519.2K

Boiling Point

2334.2K

Molar Heat

0.4790J/(mol·K)

Crystal Structure

CUB

Lattice Constant

8.890Å

Atomic Radiiatomic · covalent · van der Waals

Atomic (Empirical)

140.00pm

Covalent

119.00pm

Van der Waals

205.00pm

Electronic Propertieselectronegativity · ionization · affinity

Electron Configuration

[Ar] 3d5 4s2

Electron Shells

2, 8, 13, 2

Electronegativity

1.55Pauling

Electron Affinity

—

1st Ionization Energy

7.4kJ/mol

Oxidation States

-3, -2, -1, 0, +1, +2, +3, +4, +5, +6, +7

Orbital DiagramAufbau · Hund's rule · Pauli exclusion

↑↓
1s2
↑↓
2s2
↑↓
↑↓
↑↓
2p6
↑↓
3s2
↑↓
↑↓
↑↓
3p6
↑
↑
↑
↑
↑
3d5
↑↓
4s2

Full: 1s2 2s2 2p6 3s2 3p6 3d5 4s2Short: [Ar] 3d5 4s2

Ionization Energies (25 known)

1st7.4 kJ/mol2nd15.6 kJ/mol3rd33.7 kJ/mol4th51.2 kJ/mol5th72.4 kJ/mol6th95.6 kJ/mol7th119.2 kJ/mol8th195.5 kJ/mol9th221.9 kJ/mol10th248.6 kJ/mol11th286.1 kJ/mol12th314.4 kJ/mol13th343.6 kJ/mol14th402.9 kJ/mol15th435.2 kJ/mol16th1133.7 kJ/mol17th1224.1 kJ/mol18th1320.3 kJ/mol19th1430.9 kJ/mol20th1537.2 kJ/mol21th1643.2 kJ/mol22th1788.7 kJ/mol23th1879.9 kJ/mol24th8140.8 kJ/mol25th8572.0 kJ/molSuccessive Ionization Energies

Emission Spectrumvisible range · characteristic spectral lines

403
403
403
475
482
Mn emission
380nm750nm
403.1 nm(100%)403.4 nm(80%)403.3 nm(70%)475.4 nm(30%)482.4 nm(20%)

Abundanceby mass

🌍Earth's Crust
950.0 ppm
🌊Ocean
200.0 ppt
✨Universe
8.0 ppm
🧬Human Body
200.0 ppb

Log scale · ppm = parts per million by mass

Biological Role

Essential (trace)

Cofactor for superoxide dismutase and other enzymes. Essential for bone formation.

Discovery

Discovered By

Johann Gahn

Named By

—

Year

1774

Nuclear Data

Known Isotopes

31

Stable Isotopes

4

Stable Mass Numbers

43, 44, 45, 55

Natural isotopic abundance (IUPAC recommended values)

Isotopes of Mn31 known

NuclideZNMass (AMU)Half-lifeDecayJπAbundance
43Mnstable251843.018647Stablep5/2-—
44Mnstable251944.008009Stablep2-—
45Mnstable252044.994654Stablep5/2-—
55Mnstable253054.938043Stablestable (1%)5/2-10000.0000%
71Mn254670.982158Unknownβ⁻, β⁻n, 2n5/2-—
72Mn254771.988009Unknownβ⁻, β⁻n, 2n——
73Mn254872.992807Unknownβ⁻5/2-—
Wikipedia →Data: Bowserinator · IAEA NDS · mendeleev