36Kr83.7980 Da

Krypton

Colorless gaseous element, belongs to the noble gases. Occurs in the air, 0.0001% by volume. It can be extracted from liquid air by fractional distillation. Generally not isolated, but used with other inert gases in fluorescent lamps. Five natural isotopes, and five radioactive isotopes. Kr-85, the most stable radioactive isotope, has a half-life of 10.76 years and is produced in fission reactors. Practically inert, though known to form compounds with Fluorine.

Gallery

Vial of Glowing Ultrapure Krypton. Original size in cm: 1 x 5.

Jurii, CC BY 3.0 <https://creativecommons.org/licenses/by/3.0>, via Wikimedia Commons, source: https://images-of-elements.com/krypton.php

Bohr model of Krypton
Emission spectrum of Krypton

Emission spectrum

Physical Propertiesmass · density · phase · crystal

Atomic Mass

83.7980Da

Density

0.0034g/L

Phase (STP)

Gas

Melting Point

115.8K

Boiling Point

119.7K

Molar Heat

0.2480J/(mol·K)

Crystal Structure

FCC

Lattice Constant

5.720Å

Atomic Radiiatomic · covalent · van der Waals

Atomic (Empirical)

Covalent

117.00pm

Van der Waals

202.00pm

Electronic Propertieselectronegativity · ionization · affinity

Electron Configuration

[Ar] 3d10 4s2 4p6

Electron Shells

2, 8, 18, 8

Electronegativity

Electron Affinity

1st Ionization Energy

14.0kJ/mol

Oxidation States

0, +2

Orbital DiagramAufbau · Hund's rule · Pauli exclusion

1s2
2s2
2p6
3s2
3p6
3d10
4s2
4p6

Full: 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6Short: [Ar] 3d10 4s2 4p6

Ionization Energies (36 known)

1st14.0 kJ/mol2nd24.4 kJ/mol3rd35.8 kJ/mol4th50.9 kJ/mol5th64.7 kJ/mol6th78.5 kJ/mol7th109.1 kJ/mol8th125.8 kJ/mol9th233.0 kJ/mol10th268.0 kJ/mol11th308.0 kJ/mol12th350.0 kJ/mol13th391.0 kJ/mol14th446.0 kJ/mol15th492.0 kJ/mol16th540.0 kJ/mol17th591.0 kJ/mol18th640.0 kJ/mol19th785.3 kJ/mol20th831.6 kJ/mol21th882.8 kJ/mol22th945.0 kJ/mol23th999.0 kJ/mol24th1042.0 kJ/mol25th1155.0 kJ/mol26th1205.2 kJ/mol27th2928.9 kJ/mol28th3072.0 kJ/mol29th3228.0 kJ/mol30th3380.0 kJ/mol31th3584.0 kJ/mol32th3752.0 kJ/mol33th3971.0 kJ/mol34th4109.1 kJ/mol35th17296.4 kJ/mol36th17936.2 kJ/molSuccessive Ionization Energies

Emission Spectrumvisible range · characteristic spectral lines

557
587
427
450
432
Kr emission
380nm750nm
557.0 nm(100%)587.1 nm(60%)427.4 nm(50%)450.2 nm(40%)431.9 nm(30%)

Abundanceby mass

🌍Earth's Crust
100.0 ppt
🌊Ocean
210.0 ppt
Universe
45.0 ppm
🧬Human Body

Log scale · ppm = parts per million by mass

Biological Role

No biological role

Inert noble gas with no biological role.

Discovery

Discovered By

Sir William Ramsey, M.W. Travers

Named By

Year

1898

Nuclear Data

Known Isotopes

35

Stable Isotopes

6

Stable Mass Numbers

78, 80, 82, 83, 84, 86

Natural isotopic abundance (IUPAC recommended values)

Isotopes of Kr35 known

NuclideZNMass (AMU)Half-lifeDecayAbundance
67Kr363166.9833057.40 ms2p (0.37%), β⁺3/2-
68Kr363267.97248921.6 msβ⁺, β⁺p (0.9%), p0+
69Kr363368.96549627.9 msβ⁺ (1%), β⁺p (0.94%)5/2-
78Krstable364277.920366Stable2β⁺0+35.5000%
80Krstable364479.916378Stablestable (1%)0+228.6000%
82Krstable364681.913481Stablestable (1%)0+1159.3000%
83Krstable364782.914127Stablestable (1%)9/2+1150.0000%
84Krstable364883.911498Stablestable (1%)0+5698.7000%
86Krstable365085.910611Stable2β⁻0+1727.9000%
99Kr366398.95877640.0 msβ⁻ (1%), β⁻n (0.11%), 2n5/2-
100Kr366499.96299512.0 msβ⁻ (1%), β⁻n, 2n0+
101Kr3665100.969318Unknownβ⁻, β⁻n, 2n5/2+
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