51Sb121.7600 Da

Antimony

Element of group 15. Multiple allotropic forms. The stable form of antimony is a blue-white metal. Yellow and black antimony are unstable non-metals. Used in flame-proofing, paints, ceramics, enamels, and rubber. Attacked by oxidizing acids and halogens. First reported by Tholden in 1450.

Gallery

Antimony crystal, 2 grams, 1 cm

Unknown authorUnknown author, CC BY 3.0 <https://creativecommons.org/licenses/by/3.0>, via Wikimedia Commons, source: https://images-of-elements.com/antimony.php

Bohr model of Antimony

Physical Propertiesmass · density · phase · crystal

Atomic Mass

121.7600Da

Density

6.6800g/cm³

Phase (STP)

Solid

Melting Point

903.8K

Boiling Point

1860.2K

Molar Heat

0.2070J/(mol·K)

Crystal Structure

RHL

Lattice Constant

4.510Å

Atomic Radiiatomic · covalent · van der Waals

Atomic (Empirical)

145.00pm

Covalent

140.00pm

Van der Waals

206.00pm

Electronic Propertieselectronegativity · ionization · affinity

Electron Configuration

[Kr] 4d10 5s2 5p3

Electron Shells

2, 8, 18, 18, 5

Electronegativity

2.05Pauling

Electron Affinity

1.0kJ/mol

1st Ionization Energy

8.6kJ/mol

Oxidation States

-3, +3, +5

Orbital DiagramAufbau · Hund's rule · Pauli exclusion

1s2
2s2
2p6
3s2
3p6
3d10
4s2
4p6
4d10
5s2
5p3

Full: 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 5s2 5p3Short: [Kr] 4d10 5s2 5p3

Ionization Energies (51 known)

1st8.6 kJ/mol2nd16.6 kJ/mol3rd25.3 kJ/mol4th43.8 kJ/mol5th55.0 kJ/mol6th99.5 kJ/mol7th117.0 kJ/mol8th139.0 kJ/mol9th162.0 kJ/mol10th185.0 kJ/mol11th214.0 kJ/mol12th238.0 kJ/mol13th265.0 kJ/mol14th292.0 kJ/mol15th317.0 kJ/mol16th420.0 kJ/mol17th447.0 kJ/mol18th479.0 kJ/mol19th510.0 kJ/mol20th552.0 kJ/mol21th584.0 kJ/mol22th657.0 kJ/mol23th693.3 kJ/mol24th1214.0 kJ/mol25th1285.0 kJ/mol26th1360.0 kJ/mol27th1441.0 kJ/mol28th1518.0 kJ/mol29th1606.0 kJ/mol30th1698.0 kJ/mol31th1781.0 kJ/mol32th1869.0 kJ/mol33th1954.0 kJ/mol34th2190.0 kJ/mol35th2266.0 kJ/mol36th2349.0 kJ/mol37th2428.0 kJ/mol38th2567.0 kJ/mol39th2654.0 kJ/mol40th2815.0 kJ/mol41th2900.0 kJ/mol42th6714.0 kJ/mol43th6929.0 kJ/mol44th7167.0 kJ/mol45th7390.0 kJ/mol46th7887.0 kJ/mol47th8140.0 kJ/mol48th8455.0 kJ/mol49th8669.5 kJ/mol50th35710.0 kJ/mol51th36668.2 kJ/molSuccessive Ionization Energies

Emission Spectrumvisible range · characteristic spectral lines

600
613
475
465
Sb emission
380nm750nm
465.0 nm(100%)475.1 nm(50%)600.2 nm(40%)613.2 nm(30%)

Abundanceby mass

🌍Earth's Crust
200.0 ppb
🌊Ocean
240.0 ppt
Universe
400.0 ppt
🧬Human Body

Log scale · ppm = parts per million by mass

Biological Role

Toxic

Toxic, similar to arsenic. Antimony compounds used medicinally for leishmaniasis.

Discovery

Discovered By

Known to the ancients.

Named By

Year

Nuclear Data

Known Isotopes

41

Stable Isotopes

4

Stable Mass Numbers

102, 103, 121, 123

Natural isotopic abundance (IUPAC recommended values)

Isotopes of Sb41 known

NuclideZNMass (AMU)Half-lifeDecayAbundance
102Sbstable5151101.945142Stablep
103Sbstable5152102.939162Stablep5/2+
104Sb5153103.936344470 msβ⁺, β⁺p (0.07%), p (0.07%), α
121Sbstable5170120.903811Stablestable (1%)5/2+5721.0000%
123Sbstable5172122.904215Stablestable (1%)7/2+4279.0000%
140Sb5189139.952345170 msβ⁻ (1%), β⁻n (0.23%), 2n (0.076%)3-
141Sb5190140.957552103 msβ⁻ (1%), β⁻n, 2n7/2+
142Sb5191141.96391880.0 msβ⁻ (1%), β⁻n, 2n
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