43Tc97.9072 Da

Technetium

Radioactive metallic transition element. Can be detected in some stars and the fission products of uranium. First made by Perrier and Segre by bombarding molybdenum with deutrons, giving them Tc-97. Tc-99 is the most stable isotope with a half-life of 2.6*10^6 years. Sixteen isotopes are known. Organic technetium compounds are used in bone imaging. Chemical properties are intermediate between rhenium and manganese.

Gallery

Technetium Sample inside a sealed glass ampoule, filled with argon gas. 6x1 mm goldfoil covered with 99Tc powder (electroplated).

GFDL, CC BY-SA 4.0 <https://creativecommons.org/licenses/by-sa/4.0>, via Wikimedia Commons

Bohr model of Technetium

Physical Propertiesmass · density · phase · crystal

Atomic Mass

97.9072Da

Density

11g/cm³

Phase (STP)

Solid

Melting Point

2430.2K

Boiling Point

4535.1K

Molar Heat

Crystal Structure

HEX

Lattice Constant

2.740Å

Atomic Radiiatomic · covalent · van der Waals

Atomic (Empirical)

135.00pm

Covalent

128.00pm

Van der Waals

216.00pm

Electronic Propertieselectronegativity · ionization · affinity

Electron Configuration

[Kr] 4d5 5s2

Electron Shells

2, 8, 18, 13, 2

Electronegativity

2.10Pauling

Electron Affinity

0.6kJ/mol

1st Ionization Energy

7.1kJ/mol

Oxidation States

-3, -1, 0, +1, +2, +3, +4, +5, +6, +7

Orbital DiagramAufbau · Hund's rule · Pauli exclusion

1s2
2s2
2p6
3s2
3p6
3d10
4s2
4p6
4d5
5s2

Full: 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d5 5s2Short: [Kr] 4d5 5s2

Ionization Energies (43 known)

1st7.1 kJ/mol2nd15.3 kJ/mol3rd29.6 kJ/mol4th41.0 kJ/mol5th57.0 kJ/mol6th72.0 kJ/mol7th88.0 kJ/mol8th150.0 kJ/mol9th169.0 kJ/mol10th189.9 kJ/mol11th214.0 kJ/mol12th239.0 kJ/mol13th262.1 kJ/mol14th311.0 kJ/mol15th338.6 kJ/mol16th604.0 kJ/mol17th655.0 kJ/mol18th713.0 kJ/mol19th773.0 kJ/mol20th829.0 kJ/mol21th904.0 kJ/mol22th968.0 kJ/mol23th1032.0 kJ/mol24th1102.0 kJ/mol25th1166.0 kJ/mol26th1354.0 kJ/mol27th1411.6 kJ/mol28th1479.5 kJ/mol29th1559.0 kJ/mol30th1638.0 kJ/mol31th1689.0 kJ/mol32th1838.0 kJ/mol33th1900.3 kJ/mol34th4505.0 kJ/mol35th4681.0 kJ/mol36th4874.0 kJ/mol37th5060.0 kJ/mol38th5361.0 kJ/mol39th5570.0 kJ/mol40th5838.0 kJ/mol41th6008.4 kJ/mol42th25004.5 kJ/mol43th25787.0 kJ/molSuccessive Ionization Energies

Emission Spectrumvisible range · characteristic spectral lines

426
430
424
Tc emission
380nm750nm
426.2 nm(100%)429.7 nm(80%)423.8 nm(60%)

Abundanceby mass

Biological Role

No biological role

Radioactive; no biological role. Tc-99m is the most used medical radioisotope for imaging.

Discovery

Discovered By

Carlo Perrier, Émillo Segrè

Named By

Year

1937

Nuclear Data

Known Isotopes

40

Stable Isotopes

3

Stable Mass Numbers

83, 84, 85

Isotopes of Tc40 known

NuclideZNMass (AMU)Half-lifeDecayAbundance
83Tcstable434082.966377Stablep, β⁺, β⁺p1/2-
84Tcstable434183.959527Stablep, β⁺, β⁺p1+
85Tcstable434284.950778Stablep1/2-
120Tc4377119.96242621.0 msβ⁻ (1%), β⁻n, 2n3+
121Tc4378120.96614022.0 msβ⁻ (1%), β⁻n, 2n5/2+
122Tc4379121.971760Unknownβ⁻, β⁻n, 2n1+
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